Steve Carell ... Maxwell Smart
Anne Hathaway ... Agent 99
Dwayne Johnson ... Agent 23
Alan Arkin ... The Chief
Terence Stamp ... Siegfried
Terry Crews ... Agent 91
David Koechner ... Larabee
James Caan ... The President
Bill Murray ... Agent 13
Patrick Warburton ... Hymie
Masi Oka ... Bruce
Nate Torrence ... Lloyd
Ken Davitian ... Shtarker
David S. Lee ... Ladislas Krstic
Dalip Singh ... Dalip